Peroxisomes: Membrane-bound, micro body organelles
that Essential unsaturated fatty acid elongation C20:4 with ethyl group
-CH2-CH2- conversion to cis double bond H>C=C<H in peroxisomes
is negative ΔGHess=-61,8 kJ/mol free energy change, but minimized
reaching equilibrium mixture ΔGmin=ΔGeq=-48,1 kJ/mol.
CATALASE in complex reaction sequence favors stabile unsaturated
fatty acid product efficiency 100%:
Keq=108,43=
because erasing peroxide H2O2 to zero [H2O2]=0 mol/liter and
process velocity limits only dehydrogenase enzyme. It favors velocity
of peroxide 2H-O-O-H conversion in to biological goods
oxygen in water and heat
O2aqua + 2H2O + Q thirty million times 30106.
Two H2O2 hydrogen peroxide sources from nature
at presence of oxygen in water medium O2aqua+ H2O ,
since 500 M-years. Oxygen concentration in atmosphere 20,95%
volume fraction
(volume pro centum in air) disolutes
in pure
distilled water oxygen [O2] =2.10210-4M (mol/Liter) concentration at 25 oC.
1. Heavy metal coordinative compounds having high oxidation number
iron(III) Fe3+, Back to the catalase tutorial.
cooper(II) Cu2+ ,
manganesium(IV) Mn4+,
as well pollutant lead(IV) Pb4+ .
2. Ionization radiation:
ultraviolet UV,
x-ray,
gamma g radiation,
beta particles ( and
),
alpha particles .
Human body 70 kg mass each second chemical elements
as
carbon-14 isotopes and
potasium-40 isotopes
irradiate 7000 beta particles un
and high radiation energy absorbed forming in
O2 + H2O medium of tissues 1013 peroxide H2O2 molecules per second.
Back to the catalase tutorial.